The regiochemical outcome of Suzuki couplings of non-symmetric dibromobenzenes is investigated. Selectivities are dependent on the proximity of the bromine atom to alkene substituents, not on steric or electronic effects. Extension to a one-pot three-component Suzuki reaction leads to efficient terphenyl syntheses.
P. Zhao, M. D. Young and C. M. Beaudry, Org. Biomol. Chem., 2015, 13, 6162 DOI: 10.1039/C5OB00717H
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