[Pd(acac)(MeCN)2]BF4: air-tolerant, activator-free catalyst for alkene dimerization and polymerization

D. S. Suslov; M. V. Bykov; P. A. Abramov; M. V. Pahomova; I. A. Ushakov; V. K. Voronov; V. S. Tkach

doi:10.1039/C5RA24591E

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[Pd(acac)(MeCN)₂]BF₄: air-tolerant, activator-free catalyst for alkene dimerization and polymerization†

D. S. Suslov,*^a M. V. Bykov,^a P. A. Abramov,^bc M. V. Pahomova,^a I. A. Ushakov,^d V. K. Voronov^d and V. S. Tkach^a

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* Corresponding authors

^a Irkutsk State University, ul. K. Marksa, 1, Irkutsk, Russia
E-mail: suslov@chem.isu.ru, suslov.dmitry@gmail.com

^b Nikolaev Institute of Inorganic Chemistry SB RAS, pr-kt Akad. Lavrentieva, 3, Novosibirsk, Russia

^c Novosibirsk State University, ul. Pirogova, 2, Novosibirsk, Russia

^d National Research Irkutsk State Technical University, Lermontov St, 83, Irkutsk, Russia

Abstract

[Pd(acac)(MeCN)₂]BF₄ has been observed to catalyze selective substituted styrene dimerization and addition norbornene polymerization. Theoretical calculations based on BP86 density functional theory have been carried out to clarify the precatalyst activation mechanism.

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Article information

DOI: https://doi.org/10.1039/C5RA24591E
Article type: Communication
Submitted: 20 Nov 2015
Accepted: 26 Nov 2015
First published: 30 Nov 2015

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RSC Adv., 2015,5, 104467-104471

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[Pd(acac)(MeCN)₂]BF₄: air-tolerant, activator-free catalyst for alkene dimerization and polymerization

D. S. Suslov, M. V. Bykov, P. A. Abramov, M. V. Pahomova, I. A. Ushakov, V. K. Voronov and V. S. Tkach, RSC Adv., 2015, 5, 104467 DOI: 10.1039/C5RA24591E

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