Issue 22, 2016

The synthesis and efficient one-pot catalytic “self-breeding” of asymmetrical NC(sp3)E-hybridised pincer complexes

Abstract

Cyclopalladation of the pyridyl-substituted chiral phosphine sulfide (N–P[double bond, length as m-dash]S) and oxide (N–P[double bond, length as m-dash]O) compounds afforded the asymmetric N–C(sp3)*–S and N–C(sp3)*–O pincer complexes. When applied as catalysts in asymmetric hydrophosphination, the newly developed aliphatic pincer catalyst could be recycled over three runs and obtained in large quantities via a one-pot “self-breeding” catalytic protocol.

Graphical abstract: The synthesis and efficient one-pot catalytic “self-breeding” of asymmetrical NC(sp3)E-hybridised pincer complexes

Supplementary files

Article information

Article type
Communication
Submitted
26 Jan 2016
Accepted
17 Feb 2016
First published
17 Feb 2016

Chem. Commun., 2016,52, 4211-4214

The synthesis and efficient one-pot catalytic “self-breeding” of asymmetrical NC(sp3)E-hybridised pincer complexes

X. Yang, W. S. Tay, Y. Li, S. A. Pullarkat and P. Leung, Chem. Commun., 2016, 52, 4211 DOI: 10.1039/C6CC00763E

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