Issue 32, 2016
From the journal:

Chemical Communications

Supramolecular micelle-based nucleoapzymes for the catalytic oxidation of dopamine to aminochrome†

H. Bauke Albada,ab   Jan Willem de Vries,c   Qing Liu,c   Eyal Golub,a   Niels Klement,c   Andreas Herrmannc  and  Itamar Willner*a  

* Corresponding authors

a Institute of Chemistry, The Minerva Center for Biohybrid Complex Systems, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
E-mail: willnea@vms.huji.ac.il
Fax: +972-2-6527715
Tel: +972-2-6585272

b Laboratory of Organic Chemistry, Wageningen University, Wageningen, The Netherlands

c Zernike Institute for Advanced Materials, University of Groningen, Groningen, The Netherlands

Abstract

Lipidated DNAzymes or a lipidated Cu(II)-complex and lipidated aptamer sequences form supramolecular assemblies of micellar nucleoapzymes for the enhanced oxidation of dopamine to aminochrome. The catalytic functions of the micellar nucleoapzymes are attributed to the concentration of the substrate, using the aptamer units, in close proximity to the active sites.

Graphical abstract: Supramolecular micelle-based nucleoapzymes for the catalytic oxidation of dopamine to aminochrome

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Article information

DOI
https://doi.org/10.1039/C6CC01115B
Article type
Communication
Submitted
04 Feb 2016
Accepted
15 Mar 2016
First published
15 Mar 2016

Chem. Commun., 2016,52, 5561-5564

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Supramolecular micelle-based nucleoapzymes for the catalytic oxidation of dopamine to aminochrome

H. B. Albada, J. W. de Vries, Q. Liu, E. Golub, N. Klement, A. Herrmann and I. Willner, Chem. Commun., 2016, 52, 5561 DOI: 10.1039/C6CC01115B

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