Competing antiferromagnetic orders in the double perovskite Mn2MnReO6 (Mn3ReO6)

A. M. Arévalo-López; F. Stegemann; J. P. Attfield

doi:10.1039/C6CC01290F

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Competing antiferromagnetic orders in the double perovskite Mn₂MnReO₆ (Mn₃ReO₆)†

A. M. Arévalo-López,^a F. Stegemann^a and J. P. Attfield*^a

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* Corresponding authors

^a Centre for Science at Extreme Conditions (CSEC) and School of Chemistry, University of Edinburgh, Edinburgh EH9 3FD, UK
E-mail: j.p.attfield@ed.ac.uk

Abstract

The new double perovskite Mn₂MnReO₆ has been synthesised at high pressure. Mn²⁺ and Re⁶⁺ spins order antiferromagnetically through two successive transitions that are coupled by magnetoelastic effects, as order of the Mn spins at 109 K leads to lattice distortions that reduce frustration prompting Re order at 99 K.

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Article information

DOI: https://doi.org/10.1039/C6CC01290F
Article type: Communication
Submitted: 10 Feb 2016
Accepted: 22 Mar 2016
First published: 22 Mar 2016
This article is Open Access

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Chem. Commun., 2016,52, 5558-5560

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Competing antiferromagnetic orders in the double perovskite Mn₂MnReO₆ (Mn₃ReO₆)

A. M. Arévalo-López, F. Stegemann and J. P. Attfield, Chem. Commun., 2016, 52, 5558 DOI: 10.1039/C6CC01290F

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Chemical Communications