Issue 93, 2016
From the journal:

Chemical Communications

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)†

Wen-Ming Wan,‡ab   Andrew W. Baggett,‡c   Fei Cheng,a   Huina Lin,a   Shih-Yuan Liu*c  and  Frieder Jäkle ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Rutgers University Newark, Newark, NJ 07102, USA

b State Key Laboratory of Heavy Oil Processing and Centre for Bioengineering and Biotechnology, China University of Petroleum (East China), 66 Changjiang West Road, Qingdao Economic Development Zone, Qingdao, Shandong, People's Republic of China

c Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA

Abstract

Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from those of the all-carbon polystyrene analogues.

Graphical abstract: Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

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Article information

DOI
https://doi.org/10.1039/C6CC07332H
Article type
Communication
Submitted
08 Sep 2016
Accepted
27 Oct 2016
First published
04 Nov 2016

Chem. Commun., 2016,52, 13616-13619

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Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

W. Wan, A. W. Baggett, F. Cheng, H. Lin, S. Liu and F. Jäkle, Chem. Commun., 2016, 52, 13616 DOI: 10.1039/C6CC07332H

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