A general polymerization method is reported, which involves a direct radical coupling reaction of in situ formed benzyl-type biradicals from dibromide in the presence of a Cu(0)/ligand. The radical coupling polymerization can be employed to synthesize polyarene, polyester, polyether and polysulfone under mild conditions and within a short time.
Z. Liu and Q. Wang, RSC Adv., 2016, 6, 39568 DOI: 10.1039/C6RA02669A
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