Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N4O2 donor set

Wasinee Phonsri; Casey G. Davies; Guy N. L. Jameson; Boujemaa Moubaraki; Jas S. Ward; Paul E. Kruger; Guillaume Chastanet; Keith S. Murray

doi:10.1039/C6CC10040F

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Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N₄O₂ donor set†

Wasinee Phonsri,

^a Casey G. Davies,^b Guy N. L. Jameson,^b Boujemaa Moubaraki,^a Jas S. Ward,^c Paul E. Kruger,^c Guillaume Chastanet^d and Keith S. Murray

*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, Monash University, Clayton, Victoria, Australia
E-mail: keith.murray@monash.edu

^b Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, New Zealand

^c Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand

^d CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac 33608, France

Abstract

[Fe(qsal-Cl)₂] is one of the few known Fe(II) spin crossover compounds with an N₄O₂ donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.

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Article information

DOI: https://doi.org/10.1039/C6CC10040F
Article type: Communication
Submitted: 17 Dec 2016
Accepted: 06 Jan 2017
First published: 06 Jan 2017
This article is Open Access

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Chem. Commun., 2017,53, 1374-1377

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Symmetry breaking above room temperature in an Fe(II) spin crossover complex with an N₄O₂ donor set

W. Phonsri, C. G. Davies, G. N. L. Jameson, B. Moubaraki, J. S. Ward, P. E. Kruger, G. Chastanet and K. S. Murray, Chem. Commun., 2017, 53, 1374 DOI: 10.1039/C6CC10040F

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