Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for formic acid/CO2-mediated chemical hydrogen delivery/storage

Kohsuke Mori; Shinya Masuda; Hiromasa Tanaka; Kazunari Yoshizawa; Michel Che; Hiromi Yamashita

doi:10.1039/C7CC00864C

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Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for formic acid/CO₂-mediated chemical hydrogen delivery/storage†

Kohsuke Mori,*^abc Shinya Masuda,^a Hiromasa Tanaka,^d Kazunari Yoshizawa,^cd Michel Che^e and Hiromi Yamashita

*^ac

Author affiliations

* Corresponding authors

^a Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: mori@mat.eng.osaka-u.ac.jp, yamashita@mat.eng.osaka-u.ac.jp

^b JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama, Japan

^c Elements Strategy Initiative for Catalysts Batteries ESICB, Kyoto University, Katsura, Kyoto 615-8520, Japan

^d Institute for Materials Chemistry and IRCCS, Kyushu University, Fukuoka 819-0395, Japan

^e Institut Universitaire de France and Laboratoire de Réactivité de Surface, Université Pierre et Marie Curie, Paris 6, France

Abstract

A PdAg-based nanoparticle catalyst supported on the mesoporous silica material, SBA-15, modified with a weakly basic phenylamine functional group has been developed as a dual heterogeneous catalyst for the H₂ delivery and H₂ storage reactions mediated by formic acid and carbon dioxide.

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Article information

DOI: https://doi.org/10.1039/C7CC00864C
Article type: Communication
Submitted: 02 Feb 2017
Accepted: 14 Mar 2017
First published: 14 Mar 2017

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Chem. Commun., 2017,53, 4677-4680

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Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for formic acid/CO₂-mediated chemical hydrogen delivery/storage

K. Mori, S. Masuda, H. Tanaka, K. Yoshizawa, M. Che and H. Yamashita, Chem. Commun., 2017, 53, 4677 DOI: 10.1039/C7CC00864C

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