Issue 34, 2017

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string

Abstract

Striding to extend the length of metal-atom strings, oligo-α-pyridylamino ligands are modulated with naphthyridyl moieties leading to the undeca-nickel mixed-valence complexes [Ni11(bnatpya)4Cl2]4+ (1) and [Ni11(bnatpya)4Cl2]2+ (2). The first single-molecule conductance measurements of a linear undeca-nickel chain were performed.

Graphical abstract: A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string

Supplementary files

Article information

Article type
Communication
Submitted
10 Mar 2017
Accepted
24 Mar 2017
First published
31 Mar 2017

Chem. Commun., 2017,53, 4673-4676

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string

P. Chen, M. Sigrist, E. Horng, G. Lin, G. Lee, C. Chen and S. Peng, Chem. Commun., 2017, 53, 4673 DOI: 10.1039/C7CC01831B

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