Issue 21, 2017

A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

Abstract

We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb6Sc11W60}, {Sb8Sc7W60}, and {Sb8Sc6W60}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc3+ ions of any polyoxotungstates reported to date.

Graphical abstract: A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

Supplementary files

Article information

Article type
Communication
Submitted
11 Mar 2017
Accepted
26 Apr 2017
First published
26 Apr 2017

Dalton Trans., 2017,46, 6848-6852

A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates

Z. Cai, T. Yang, Y. Qi, X. Li and S. Zheng, Dalton Trans., 2017, 46, 6848 DOI: 10.1039/C7DT00892A

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