A new family of clusters containing a silver-centered tetracapped [Ag@Ag4(μ3-P)4] tetrahedron, inscribed within a N12 icosahedron

Alexander V. Artem'ev; Irina Yu. Bagryanskaya; Evgeniya P. Doronina; Peter M. Tolstoy; Artem L. Gushchin; Mariana I. Rakhmanova; Alexander Yu. Ivanov; Anastasiya O. Suturina

doi:10.1039/C7DT02597A

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A new family of clusters containing a silver-centered tetracapped [Ag@Ag₄(μ₃-P)₄] tetrahedron, inscribed within a N₁₂ icosahedron†

Alexander V. Artem'ev,

*^a Irina Yu. Bagryanskaya,^bc Evgeniya P. Doronina,^d Peter M. Tolstoy,

^e Artem L. Gushchin,^ac Mariana I. Rakhmanova,^a Alexander Yu. Ivanov^e and Anastasiya O. Suturina^d

Author affiliations

* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Akad. Lavrentiev Ave., Novosibirsk 630090, Russia
E-mail: chemisufarm@yandex.ru

^b N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Akad. Lavrentiev Ave., Novosibirsk 630090, Russia

^c Novosibirsk State University, National Research University, Department of Natural Sciences, 2, Pirogova Str., Novosibirsk 630090, Russia

^d A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russia

^e St. Petersburg State University, Center for Magnetic Resonance, Universitetskij pr. 26, St. Petersburg 198504, Russia

Abstract

An unprecedented silver-centered P-tetracapped [Ag@Ag₄(μ₃-P)₄] tetrahedron inscribed within a N₁₂ icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting Ag^I salts with tris(2-pyridyl)phosphine (Py₃P).

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Article information

DOI: https://doi.org/10.1039/C7DT02597A
Article type: Communication
Submitted: 17 Jul 2017
Accepted: 23 Aug 2017
First published: 24 Aug 2017
This article is Open Access

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Dalton Trans., 2017,46, 12425-12429

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A new family of clusters containing a silver-centered tetracapped [Ag@Ag₄(μ₃-P)₄] tetrahedron, inscribed within a N₁₂ icosahedron

A. V. Artem'ev, I. Yu. Bagryanskaya, E. P. Doronina, P. M. Tolstoy, A. L. Gushchin, M. I. Rakhmanova, A. Yu. Ivanov and A. O. Suturina, Dalton Trans., 2017, 46, 12425 DOI: 10.1039/C7DT02597A

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Dalton Transactions