Issue 38, 2017
From the journal:

Dalton Transactions

Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(ii) clusters†

Jun-Li Wang,a   Yan Bai,*a   Hui Pan,a   Guang-Shui Zhenga  and  Dong-Bin Dang ORCID logo *a  

* Corresponding authors

a Henan Key Laboratory of Polyoxometalate chemistry, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P.R. China
E-mail: baiyan@henu.edu.cn, dangdb@henu.edu.cn
Fax: (+86)-371-23881589
Tel: (+86)-371-23881589

Abstract

A novel three-dimensional metal–organic framework [Ni3(BTC)2(bpp)2(H2O)]·3H2O (1) based on mixed ligands H3BTC (1,2,4-benzenetricarboxylic acid) and bpp (1,3-bis(4-pyridyl)propane) was obtained under hydrothermal conditions. Crystal structure analysis reveals that 1 is a framework based on cage-like Ni8(COO)12 units. Furthermore, long-range magnetic ordering is observed at low temperature.

Graphical abstract: Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(ii) clusters

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Article information

DOI
https://doi.org/10.1039/C7DT02889J
Article type
Communication
Submitted
05 Aug 2017
Accepted
06 Sep 2017
First published
06 Sep 2017

Dalton Trans., 2017,46, 12771-12774

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Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(II) clusters

J. Wang, Y. Bai, H. Pan, G. Zheng and D. Dang, Dalton Trans., 2017, 46, 12771 DOI: 10.1039/C7DT02889J

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