Issue 4, 2017
From the journal:

Organic & Biomolecular Chemistry

Synthesis of different types of alkoxy fullerene derivatives from chlorofullerene C60Cl6†

Ekaterina A. Khakina,a   Ol'ga A. Kraevaya,ab   Maria L. Popova,ab   Alexander S. Peregudov,c   Sergey I. Troyanov,d   Alexander V. Chernyak,a   Vyacheslav M. Martynenko,a   Alexander V. Kulikov,a   Dominique Scholse  and  Pavel A. Troshin*af  

* Corresponding authors

a IPCP RAS, Semenov Prospect 1, Chernogolovka, Russia
E-mail: troshin2003@inbox.ru
Fax: +7 496522 3507
Tel: +7 496522 1418

b HCC RAS, Miusskaya pl. 9, Moscow, Russia

c INEOS RAS, Vavylova St. 28, B-334, Moscow, Russia

d Department of Chemistry, Moscow State University, Leninskie gory, Moscow, Russia

e Rega Institute for Medical Research, KU Leuven, Minderbroedersstraat 10, Leuven, Belgium

f Skolkovo Institute of Science and Technology, Nobel St. 3, Moscow, Russian Federation

Abstract

We report novel synthetic routes for facile preparation of highly functionalized fullerene derivatives C60(OR)5X (X = H, Cl, Br), C60(OR)4O and C60(OR)2 from chlorofullerene C60Cl6. The first water-soluble fullerene compound bearing residues of 3-oxypropanoic acid demonstrated a potent anti-HIV activity.

Graphical abstract: Synthesis of different types of alkoxy fullerene derivatives from chlorofullerene C60Cl6

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Article information

DOI
https://doi.org/10.1039/C6OB02251K
Article type
Communication
Submitted
15 Oct 2016
Accepted
01 Nov 2016
First published
01 Nov 2016

Org. Biomol. Chem., 2017,15, 773-777

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Synthesis of different types of alkoxy fullerene derivatives from chlorofullerene C60Cl6

E. A. Khakina, O. A. Kraevaya, M. L. Popova, A. S. Peregudov, S. I. Troyanov, A. V. Chernyak, V. M. Martynenko, A. V. Kulikov, D. Schols and P. A. Troshin, Org. Biomol. Chem., 2017, 15, 773 DOI: 10.1039/C6OB02251K

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