The first seco-casbane, EBC-329, isolated from the Australian rainforest, was synthesised from (+)-2-carene in seven steps. This endeavour not only established the absolute stereochemical assignment as (8R,9S)-EBC-329, but also identified, via photoisomerisation, a new seco-casbane family member.
T. J. Vanden Berg, D. M. Pinkerton and C. M. Williams, Org. Biomol. Chem., 2017, 15, 7102 DOI: 10.1039/C7OB01400G
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