Intramolecular strong electronic coupling in a discretely H-aggregated phthalocyanine dimer connected with a rigid linker

Abstract

Preparation of an accurate assembly of phthalocyanines is rather difficult because of the high aggregation property of phthalocyanines. In this study, a novel discrete phthalocyanine dimer was prepared in which the relative configuration of each component was tightly and accurately fixed in an H-aggregate form by a rigid U-shaped linker. Electrochemical measurements showed that there were strong intramolecular electronic interactions between the two phthalocyanines.