Issue 64, 2018

Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution

Abstract

Artificial vesicles can aid in the study and understanding of biological cell membranes. This study employs pnictogen bonding to actively direct the self-assembly of a true reversed bilayer. Antimony(III) alkoxide cages that self-assemble through multiple strong Sb⋯O interactions propagate in two dimensions to form a reverse bilayer structure in the solid state. Long alkyl tails allow these reverse bilayers to be processed into vesicles in solution that are a reverse of biological cell membranes.

Graphical abstract: Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2018
Accepted
17 Jul 2018
First published
18 Jul 2018

Chem. Commun., 2018,54, 8849-8852

Author version available

Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution

S. Moaven, J. Yu, M. Vega, D. K. Unruh and A. F. Cozzolino, Chem. Commun., 2018, 54, 8849 DOI: 10.1039/C8CC05187A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements