Polymorphism of a porous hydrogen bond-assisted ionic organic framework

Dániel Vajk Horváth; Tamás Holczbauer; Laura Bereczki; Roberta Palkó; Nóra Veronika May; Tibor Soós; Petra Bombicz

doi:10.1039/C8CE00041G

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Polymorphism of a porous hydrogen bond-assisted ionic organic framework†

Dániel Vajk Horváth,

^a Tamás Holczbauer,

*^ab Laura Bereczki,

^b Roberta Palkó,

^a Nóra Veronika May,

^b Tibor Soós

^a and Petra Bombicz

Author affiliations

* Corresponding authors

^a Institute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Magyar tudósok körútja 2, 1117 Budapest, Hungary
E-mail: holczbauer.tamas@ttk.mta.hu

^b Chemical Crystallography Research Laboratory, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Magyar tudósok körútja 2, 1117 Budapest, Hungary

Abstract

The polymorphism of a porous, non-covalently bonded ionic organic framework is reported. The framework is constructed by hydrogen bonding and anion⋯π interactions. In a solvatomorphic lattice, pyridine takes part in the framework formation. The role of molecular rigidity in framework construction is proven by analogous non-porous crystals, where polymorphism also appears.

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DOI: https://doi.org/10.1039/C8CE00041G
Article type: Communication
Submitted: 09 Jan 2018
Accepted: 26 Feb 2018
First published: 02 Mar 2018
This article is Open Access

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CrystEngComm, 2018,20, 1779-1782

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Polymorphism of a porous hydrogen bond-assisted ionic organic framework

D. V. Horváth, T. Holczbauer, L. Bereczki, R. Palkó, N. V. May, T. Soós and P. Bombicz, CrystEngComm, 2018, 20, 1779 DOI: 10.1039/C8CE00041G

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CrystEngComm

Polymorphism of a porous hydrogen bond-assisted ionic organic framework†

Abstract

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Polymorphism of a porous hydrogen bond-assisted ionic organic framework

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