The thermal expansion properties of a newly synthesized mixed metal mixed organic MOF has been studied by variable temperature single crystal X-ray diffraction. The rare area NTE and large PTE of the MOF have been rationalized by an “elevator-platform” mechanism induced by O–H⋯O hydrogen bonding connecting the 2D layers in the crystal structure.
A. Shrivastava, L. Negi and D. Das, CrystEngComm, 2018, 20, 4719 DOI: 10.1039/C8CE00939B
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