Issue 18, 2018

Electrocatalytic degradation of rice straw lignin in alkaline solution through oxidation on a Ti/SnO2–Sb2O3/α-PbO2/β-PbO2 anode and reduction on an iron or tin doped titanium cathode

Abstract

A novel procedure for selective production of biomass-based compounds by electrochemical conversion has been developed in this work. At ambient pressure and mild temperature, rice straw lignin dissolved in sodium hydroxide solution was directly electro-oxidized on the surface of a Ti/SnO2–Sb2O3/α-PbO2/β-PbO2 anode, and subsequently, electro-reduction by the electro-generated chemisorbed hydrogen on the titanium-based (iron or tin doped titanium) cathodes proceeded. The electro-catalysis could effectively break the chemical linkages among phenylpropyl units in rice straw lignin, and more than 16 kinds of aromatic compounds containing phenols, aromatic hydrocarbon, aromatic ester, aromatic ketone, aromatic acid and aromatic aldehyde (e.g. guaiacol, syringol, dihydroeugenol, vanillin, p-coumaric acid, ferulic acid, etc.) were generated and identified utilizing GC-MS measurement. The operation conditions for the enhancement of the product yield including the current density, lignin concentration, temperature and reaction time were optimized. The results indicate that the properties of the cathode materials, current density and reaction time play important roles in the electrocatalytic hydrogenation of rice straw lignin.

Graphical abstract: Electrocatalytic degradation of rice straw lignin in alkaline solution through oxidation on a Ti/SnO2–Sb2O3/α-PbO2/β-PbO2 anode and reduction on an iron or tin doped titanium cathode

Article information

Article type
Paper
Submitted
16 Feb 2018
Accepted
08 Aug 2018
First published
08 Aug 2018

Catal. Sci. Technol., 2018,8, 4665-4677

Electrocatalytic degradation of rice straw lignin in alkaline solution through oxidation on a Ti/SnO2–Sb2O3/α-PbO2/β-PbO2 anode and reduction on an iron or tin doped titanium cathode

Y. Jia, Y. Wen, X. Han, J. Qi, Z. Liu, S. Zhang and G. Li, Catal. Sci. Technol., 2018, 8, 4665 DOI: 10.1039/C8CY00307F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements