Superior solar-to-hydrogen energy conversion efficiency by visible light-driven hydrogen production via highly reduced Ti2+/Ti3+ states in a blue titanium dioxide photocatalyst

Abstract

Photocatalytic water splitting is one of the most important renewable paths and a reliable hydrogen production system. In most successful molecular and supramolecular biomimetic hydrogen production methods, a photosensitizer and a catalyst were constructed where the photoexcited electron in the photosensitizer is transferred either inter- or intramolecularly to the catalytic centre. Similar to supramolecular complexes in a photocatalytic hydrogen production scheme, here we develop a redox system that contains Ti³⁺/Ti²⁺ reduced states in TiO₂ which act as both visible light harvesting components and the catalytic sites for the catalytic hydrogen production with visible-near infrared photons. The Ti³⁺/Ti²⁺ states in TiO₂ produce hydrogen from pure water with a solar-to-hydrogen energy conversion efficiency of 0.89% and a quantum yield of 43% at 655 nm. The mechanism of hydrogen production by the Ti³⁺/Ti²⁺ reduced states in TiO₂ involves the initial generation of highly air stable and highly reduced Ti³⁺ and Ti²⁺ states in TiO₂ by the formation of an AlOOH layer surrounding the anatase and rutile particles. Once Ti³⁺ and Ti²⁺ states are generated, these states are continuously self-generated via absorption of visible-near infrared radiation where hydrogen is produced by the transfer of electrons from Ti³⁺/Ti²⁺ to H⁺.