[Zr6O4(OH)4(benzene-1,4-dicarboxylato)6]n: a hexagonal polymorph of UiO-66

Maite Perfecto-Irigaray; Garikoitz Beobide; Oscar Castillo; Ivan da Silva; Daniel García-Lojo; Antonio Luque; Ander Mendia; Sonia Pérez-Yáñez

doi:10.1039/C9CC00802K

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[Zr₆O₄(OH)₄(benzene-1,4-dicarboxylato)₆]_n: a hexagonal polymorph of UiO-66†

Maite Perfecto-Irigaray,

^a Garikoitz Beobide,

*^a Oscar Castillo,

*^a Ivan da Silva,

^b Daniel García-Lojo,

^a Antonio Luque,

^a Ander Mendia

^a and Sonia Pérez-Yáñez

^ac

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco/Euskal Herriko Unibertsitatea, UPV/EHU, Apartado 644, E-48080 Bilbao, Spain
E-mail: garikoitz.beobide@ehu.eus, oscar.castillo@ehu.eus

^b ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX, UK

^c Departamento de Química Inorgánica, Facultad de Farmacia, Universidad del País Vasco/Euskal Herriko Unibertsitatea, UPV/EHU, E-01006 Vitoria-Gasteiz, Spain

Abstract

Since its discovery in 2008, the paradigmatic UiO-66 has behaved as the germ that has prompted the chemistry of group-4 metal based metal–organic frameworks, all of them featuring outstanding thermal and chemical stability. Herein we present the first polymorph of UiO-66 and the key conditions that led to its formation.

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Article information

DOI: https://doi.org/10.1039/C9CC00802K
Article type: Communication
Submitted: 28 Jan 2019
Accepted: 25 Apr 2019
First published: 25 Apr 2019

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Chem. Commun., 2019,55, 5954-5957

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[Zr₆O₄(OH)₄(benzene-1,4-dicarboxylato)₆]_n: a hexagonal polymorph of UiO-66

M. Perfecto-Irigaray, G. Beobide, O. Castillo, I. da Silva, D. García-Lojo, A. Luque, A. Mendia and S. Pérez-Yáñez, Chem. Commun., 2019, 55, 5954 DOI: 10.1039/C9CC00802K

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