Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets

Angelos B. Canaj; Mukesh Kumar Singh; Emma Regincós Marti; Marko Damjanović; Claire Wilson; Oscar Céspedes; Wolfgang Wernsdorfer; Gopalan Rajaraman; Mark Murrie

doi:10.1039/C9CC00965E

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Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets†

Angelos B. Canaj,

^a Mukesh Kumar Singh,^b Emma Regincós Marti,

^a Marko Damjanović,^cd Claire Wilson,

^a Oscar Céspedes,^e Wolfgang Wernsdorfer,

^cd Gopalan Rajaraman

*^b and Mark Murrie

*^a

Author affiliations

* Corresponding authors

^a WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: mark.murrie@glasgow.ac.uk

^b Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, India
E-mail: rajaraman@chem.iitb.ac.in

^c Physikalisches Institut (PHI), Karlsruhe Institute of Technology, Wolfgang-Gaede-Strasse 1, 76131 Karlsruhe, Germany

^d Institute of Nanotechnology (INT), Karlsruhe Institute of Technology, Hermann-von-Helmholz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

^e School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, UK

Abstract

A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate U_cal barriers of over 600 K.

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DOI: https://doi.org/10.1039/C9CC00965E
Article type: Communication
Submitted: 01 Feb 2019
Accepted: 29 Apr 2019
First published: 29 Apr 2019
This article is Open Access

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Chem. Commun., 2019,55, 5950-5953

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Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets

A. B. Canaj, M. K. Singh, E. Regincós Marti, M. Damjanović, C. Wilson, O. Céspedes, W. Wernsdorfer, G. Rajaraman and M. Murrie, Chem. Commun., 2019, 55, 5950 DOI: 10.1039/C9CC00965E

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Chemical Communications

Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets†

Abstract

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Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets

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