Photophysical deactivation behaviour of Rhodamine B using different graphite materials

Abstract

In the present work, an attempt has been made to elucidate the structural features of synthesized graphite materials, i.e., expanded graphite (EG) and an expanded graphite/silver nanoparticles (EG/AgNPs) nanocomposite. In order to obtain knowledge about the functional groups present, the interlayer spacing between the carbon layers, topographical features, and the characterization of the materials were carried out using Fourier-transformer infrared spectroscopy, X-ray diffraction, Raman spectroscopy, field emission scanning electron microscopy-energy dispersive X-ray spectroscopy and atomic force microscope. Furthermore, the quenching efficiency of the synthesized graphite materials was also compared using Rhodamine B (Rhd B) as a fluorescent probe. The non-linear behaviour of the Stern–Volmer plots suggested that the complex quenching mechanism (a combination of static and dynamic quenching) was responsible for the decrease in photoluminescence intensity. At a lower concentration of the quencher, the static quenching mechanism was dominant whereas at a higher concentration dynamic processes seemed to be more likely. The binding strength of the complexation between the fluorophore and the quencher at lower concentrations was studied in detail for both of the synthesized materials. The analysis showed that the EG/AgNPs exhibited better quenching efficiency and possessed a strong binding strength in comparison to EG. The thermodynamic parameters of this association suggested that the interaction process was spontaneous and exothermic in nature. Thus, this work offers helpful insights into the fluorescence quenching mechanisms of the Rhd B/EG and its composite system.