The controlled synthesis of 1,4-naphthoquinones and tetraphene-7,12-diones, which bear the ABCD-ring of landomycins, has been accomplished directly through oxidative rearrangement of common stable precursors, namely, previously non-isolable cyclobuta[a]naphthalen-4(2H)-ones.
F. Herrera, A. Luna, I. Fernández and P. Almendros, Chem. Commun., 2020, 56, 1290 DOI: 10.1039/C9CC08628E
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