Issue 50, 2020
From the journal:

Chemical Communications

Turning on solid-state phosphorescence of platinum acetylides with aromatic stacking†

William J. Mullin,a   Huan Qin,b   Tomoyasu Mani, ORCID logo c   Peter Müller, ORCID logo d   Matthew J. Panzer ORCID logo b  and  Samuel W. Thomas ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Tufts University, 62 Talbot Ave, Medford, MA 02155, USA
E-mail: sam.thomas@tufts.edu

b Department of Chemical and Biological Engineering, Tufts University, 4 Colby Street, Medford, MA 02155, USA

c Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, USA

d Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

Abstract

Neat solids that phosphoresce under ambient conditions are rare due to aggregation-caused quenching. This communication describes a platinum acetylide (PtPE) that phosphoresces as a solid due to programmed aromatic stacking interactions of pendant groups that prevent intermolecular aggregation.

Graphical abstract: Turning on solid-state phosphorescence of platinum acetylides with aromatic stacking

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC02119A
Article type
Communication
Submitted
22 Mar 2020
Accepted
11 May 2020
First published
20 May 2020

Chem. Commun., 2020,56, 6854-6857

Author version available


Download author version (PDF)

Permissions

Request permissions

Turning on solid-state phosphorescence of platinum acetylides with aromatic stacking

W. J. Mullin, H. Qin, T. Mani, P. Müller, M. J. Panzer and S. W. Thomas, Chem. Commun., 2020, 56, 6854 DOI: 10.1039/D0CC02119A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements