1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5–20-fold lower initial rates of degradation than BDPA.
S. Mandal and S. Th. Sigurdsson, Chem. Commun., 2020, 56, 13121 DOI: 10.1039/D0CC04920D
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