Issue 86, 2020
From the journal:

Chemical Communications

Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene†

Mengna Tao,a   Wenbo Li*a  and  Junliang Zhang ORCID logo *abc  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. China
E-mail: wbli@chem.ecnu.edu.cn

b Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, P. R. China
E-mail: junliangzhang@fudan.edu.cn

c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS, 345 Lingling Road, Shanghai, P. R. China

Abstract

A highly enantioselective Pd/Xiang-Phos-catalyzed carbohetero-functionalization of norbornene is described, giving a direct access to various chiral norbornane-fused dihydrofurans and dihydro-pyrroles. This synthetic methodology provides the first example of asymmetric carboetherification of norbornene, and also tolerates norbornadiene well.

Graphical abstract: Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene

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Article information

DOI
https://doi.org/10.1039/D0CC04996D
Article type
Communication
Submitted
21 Jul 2020
Accepted
15 Sep 2020
First published
18 Sep 2020

Chem. Commun., 2020,56, 13125-13128

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Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene

M. Tao, W. Li and J. Zhang, Chem. Commun., 2020, 56, 13125 DOI: 10.1039/D0CC04996D

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