Effective photocatalytic degradation and physical adsorption of methylene blue using cellulose/GO/TiO2 hydrogels

Abstract

Environmentally friendly cellulose/GO/TiO₂ hydrogel photocatalyst has been successfully fabricated via a green, simple, and one-step method and evaluated as the photocatalyst and adsorbent for the removal of methylene blue (MB). The XRD and FTIR analysis suggested the strong interaction among cellulose, GO and TiO₂, resulting from the formation of hydrogen bonds. Due to the unique porous structure of cellulose hydrogel and introduction of GO, the cellulose/GO/TiO₂ hydrogel showed superior (degradation ratio ∼ 93%) and reproducible (no significant change during the ten consecutive cycles) performance in the removal of MB under UV light. Consequently, the prepared cellulose/GO/TiO₂ hydrogel can be applied as an eco-friendly, high-performance, reproducible, and stable photocatalyst and adsorbent for the removal of MB. This green hydrogel is a promising candidate for dye wastewater treatment. Moreover, this work is expected to extend the scope of bio-templated synthesis of other nanomaterials for various applications.