Microwave dielectric properties of low-temperature-fired MgNb2O6 ceramics for LTCC applications

Abstract

MgNb₂O₆ ceramics doped with (Li₂O–MgO–ZnO–B₂O₃–SiO₂) glass were synthesized by the traditional solid phase reaction route. The effects of LMZBS addition on microwave dielectric properties, grain growth, phase composition and morphology of MgNb₂O₆ ceramics were studied. The SEM results show dense and homogeneous microstructure with grain size of 1.72 μm. Raman spectra and XRD patterns indicate the pure phase MgNb₂O₆ ceramic. The experimental results show that LMZBS glass can markedly decrease the sintering temperature from 1300 °C to 925 °C. Higher density and lower porosity make ceramics have better dielectric properties. The MgNb₂O₆ ceramic doped with 1 wt% LMZBS glass sintered at 925 °C for 5 h, possessed excellent dielectric properties: ε_r = 19.7, Q·f = 67 839 GHz, τ_f = −41.01 ppm °C⁻¹. Moreover, the favorable chemical compatibility of the MgNb₂O₆ ceramic with silver electrodes makes it as promising material for low temperature co-fired ceramic (LTCC) applications.