Issue 9, 2022

Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

Abstract

Recent results indicate a halogen bond donor is strengthened through direct interaction with a hydrogen bond to the electron-rich belt of the halogen. Here, this Hydrogen Bond enhanced Halogen Bond (HBeXB) plays a clear role in a catalyst. Our HBeXB catalyst improves product conversion in a halide abstraction reaction over a traditional halogen bonding derivative.

Graphical abstract: Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

Supplementary files

Article information

Article type
Communication
Submitted
17 Nov 2021
Accepted
13 Dec 2021
First published
16 Dec 2021

Chem. Commun., 2022,58, 1378-1381

Author version available

Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

A. M. S. Riel, D. A. Decato, J. Sun and O. B. Berryman, Chem. Commun., 2022, 58, 1378 DOI: 10.1039/D1CC05475A

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