This study describes the synthesis of the first aziridinium-based compounds, namely hybrid perovskites (AzrH)PbHal3 (where AzrH = aziridinium, Hal = Cl, Br or I). This highly reactive species was stabilized in 3D lead halide frameworks and was found to be a small enough organic cation to promote the formation of semiconducting organo-inorganic materials.
H. R. Petrosova, O. I. Kucheriv, S. Shova and I. A. Gural'skiy, Chem. Commun., 2022, 58, 5745 DOI: 10.1039/D2CC01364A
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