Issue 38, 2022
From the journal:

Chemical Communications

A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes†

Jiaxin Tian,a   Marie Cordier,b   Christophe Bour, ORCID logo a   Audrey Auffrant ORCID logo *b  and  Vincent Gandon ORCID logo *ab  

* Corresponding authors

a Institut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS UMR 8182, Université Paris-Saclay, Bâtiment 420, 91405 Orsay cedex, France
E-mail: vincent.gandon@universite-paris-saclay.fr

b Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168 Ecole Polytechnique, Institut Polytechnique de Paris, route de Saclay, 91120 Palaiseau, France
E-mail: audrey.auffrant@polytechnique.edu

Abstract

The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(I) salt. DFT study of this compound reveals the low valent character of the N(I) center.

Graphical abstract: A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2CC01637K
Article type
Communication
Submitted
22 Mar 2022
Accepted
14 Apr 2022
First published
18 Apr 2022

Chem. Commun., 2022,58, 5741-5744

Permissions

Request permissions

A cyclic divalent N(I) species isoelectronic to carbodiphosphoranes

J. Tian, M. Cordier, C. Bour, A. Auffrant and V. Gandon, Chem. Commun., 2022, 58, 5741 DOI: 10.1039/D2CC01637K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements