Issue 65, 2022
From the journal:

Chemical Communications

A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation†

Nereida Hidalgo, ORCID logo ‡a   Felipe de la Cruz-Martínez, ORCID logo ‡a   M. Trinidad Martín,b   M. Carmen Nicasio ORCID logo *b  and  Jesús Campos ORCID logo *a  

* Corresponding authors

a Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Avenida Américo Vespucio 49, Sevilla 41092, Spain
E-mail: Spainjesus.campos@iiq.csic.es

b Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, Sevilla 41071, Spain
E-mail: mnicasio@us.es

Abstract

A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(II) structure.

Graphical abstract: A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

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Article information

DOI
https://doi.org/10.1039/D2CC03089F
Article type
Communication
Submitted
31 May 2022
Accepted
19 Jul 2022
First published
19 Jul 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 9144-9147

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A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

N. Hidalgo, F. de la Cruz-Martínez, M. T. Martín, M. C. Nicasio and J. Campos, Chem. Commun., 2022, 58, 9144 DOI: 10.1039/D2CC03089F

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