Issue 32, 2022

Preparation of a Mg2+-containing MOF through ion exchange and its high ionic conductivity

Abstract

We report, for the first time, the preparation and ionic conductivity of a Mg2+-containing metal–organic framework (MOF) having type A features, i.e., an anionic framework containing Mg2+ as the counter cation. We prepared Mg3[(MnMo6O18)2L] (L12− = C{C6H4CH[double bond, length as m-dash]NC(CH2O)3}412−) (MOF-688-Mg) through a simple ion exchange reaction, and it showed high ionic conductivity above 10−5 S cm−1 at 25 °C under MeCN vapor.

Graphical abstract: Preparation of a Mg2+-containing MOF through ion exchange and its high ionic conductivity

Supplementary files

Article information

Article type
Communication
Submitted
06 Jul 2022
Accepted
29 Jul 2022
First published
30 Jul 2022
This article is Open Access
Creative Commons BY license

Dalton Trans., 2022,51, 12037-12040

Preparation of a Mg2+-containing MOF through ion exchange and its high ionic conductivity

S. Niwa and M. Sadakiyo, Dalton Trans., 2022, 51, 12037 DOI: 10.1039/D2DT02166H

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