Issue 32, 2022

Synthesis, crystal structure, EPR, and DFT studies of an unusually distorted vanadium(ii) complex

Abstract

We report the synthesis and structure of the most highly distorted four-coordinate d3 ion known to date that also serves as the second known example of a bis(biphenolato) transition metal complex. We demonstrate the application of density functional theory to calculate the magnetic parameters derived from the experimental and simulated EPR spectra.

Graphical abstract: Synthesis, crystal structure, EPR, and DFT studies of an unusually distorted vanadium(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2022
Accepted
26 Jul 2022
First published
28 Jul 2022

Dalton Trans., 2022,51, 12031-12036

Author version available

Synthesis, crystal structure, EPR, and DFT studies of an unusually distorted vanadium(II) complex

P. Charles, M. E. Gaspard, S. Alvarez, M. S. Ziegler, A. Baldansuren, W. H. Armstrong, K. V. Lakshmi and P. J. Bonitatibus, Dalton Trans., 2022, 51, 12031 DOI: 10.1039/D2DT02392J

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