Issue 24, 2022

Synthesis of an ABC triblock copolymer by a bilateral Click reaction using α,ω-bifunctionalized poly(3-hexylthiophene) as an inner segment

Abstract

A novel ABC-type triblock copolymer, where A, B, and C were poly(methyl methacrylate) (PMMA), P3HT, and polystyrene (PS), respectively, was successfully synthesized by the bilateral Cu-catalyzed azide alkyne cycloaddition (CuAAC) reaction of α,ω-bifunctionalized P3HT with α-chain-end-functionalized PMMA and ω-chain-end-functionalized PS at a high yield.

Graphical abstract: Synthesis of an ABC triblock copolymer by a bilateral Click reaction using α,ω-bifunctionalized poly(3-hexylthiophene) as an inner segment

Supplementary files

Article information

Article type
Communication
Submitted
25 Mar 2022
Accepted
18 May 2022
First published
20 May 2022

Polym. Chem., 2022,13, 3613-3618

Synthesis of an ABC triblock copolymer by a bilateral Click reaction using α,ω-bifunctionalized poly(3-hexylthiophene) as an inner segment

S. Inagaki and T. Higashihara, Polym. Chem., 2022, 13, 3613 DOI: 10.1039/D2PY00370H

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