Effect of sequence distribution of block copolymers on the interfacial properties of ternary mixtures: a dissipative particle dynamics simulation

Abstract

In this paper, the dissipative particle dynamics (DPD) simulations method is used to study the effect of sequence distribution of block copolymers on the interfacial properties between immiscible homopolymers. Five block copolymers with the same composition but different sequence lengths are utilized for simulation. The sequence distribution is varied from the alternating copolymer to the symmetric diblock copolymer. Our simulations show that the efficiency of the block copolymer in reducing the interfacial tension is highly dependent on both the degree of penetration of the copolymer chain into the homopolymer phase and the number of copolymers at the interface per area. The linear block copolymers AB with the sequence length of τ = 8 could both sufficiently extend into the homopolymer phases and exhibit a larger number of copolymers at the interface per area. Thereby the copolymer with the sequence length τ = 8 is more effective in reducing the interfacial tension compared to that of diblock copolymers and the alternating copolymers at the same concentration. This work offers useful tips for copolymer compatibilizer selection at the immiscible homopolymer mixture interfaces.