Rapid determination of lambda-cyhalothrin residues on Chinese cabbage based on MIR spectroscopy and a Gustafson–Kessel noise clustering algorithm

Abstract

Pesticide residues exceeding the standard in Chinese cabbage is harmful to human health. In order to quickly, non-destructively and effectively qualitatively analyze lambda-cyhalothrin residues on Chinese cabbage, a method involving a Gustafson–Kessel noise clustering (GKNC) algorithm was proposed to cluster the mid-infrared (MIR) spectra. A total of 120 Chinese cabbage samples with three different lambda-cyhalothrin residue levels (no lambda-cyhalothrin, and cases where the ratios of lambda-cyhalothrin and water were 1 : 500 and 1 : 100) were scanned using an Agilent Cary 630 FTIR spectrometer for collecting the MIR spectra. Next, multiple scatter correction (MSC) was employed to eliminate the effects of light scattering. Furthermore, principal component analysis (PCA) and linear discriminant analysis (LDA) were utilized to reduce the dimensionality and extract the feature information from the MIR spectra. Finally, fuzzy c-means (FCM) clustering, Gustafson–Kessel (GK) clustering, noise clustering (NC) and the GKNC algorithm were applied to cluster the MIR spectral data, respectively. The experimental results showed that the GKNC algorithm gave the best classification performance compared against the other three fuzzy clustering algorithms, and its highest clustering accuracy reached 93.3%. Therefore, the GKNC algorithm coupled with MIR spectroscopy is an effective method for detecting lambda-cyhalothrin residues on Chinese cabbage.