Synthesis of multicolor-emitting nitrogen–sulfur co-doped carbon dots and their photochemical studies for sensing applications

Abstract

Photoluminescent carbon dots (CDs) possess several advantages, which include high stability and a non-toxicity that are essential in different applications such as catalysis, drug delivery, and sensors. The presence of heteroatoms modifies their physicochemical characteristics. In this work, a combination of CDs is manufactured utilizing a solvothermal technique using citric acid and thiourea. After separating each section using column chromatography, green and yellow CDs with average diameters of 8.3 and 7.0 nm, respectively, are generated. Next, optical and structural characterizations indicated that the variation in the emission color was caused by differences in surface functional groups rather than particle size. The photoelectrochemical properties are explored by including quinone derivatives and metal ions, which are quenchers for the CDs. The photoluminescence quenching results showed the presence of anionic functional groups on the surface of the CDs. Furthermore, these functional groups interacted strongly with particular types of metal ions, indicating that they may be employed as metal ion sensors.