Visible-light-induced Csp3–H functionalization of glycine derivatives by cerium catalysis

Shutao Wang; Yanjie Ye; Yansong Hu; Xu Meng; Zhao Liu; Jiyu Liu; Kuan Chen; Zhengze Zhang; Yuan Zhang

doi:10.1039/D2CC07071E

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Visible-light-induced C_sp³–H functionalization of glycine derivatives by cerium catalysis†

Shutao Wang,

‡^a Yanjie Ye,‡^a Yansong Hu,^a Xu Meng,^b Zhao Liu,^b Jiyu Liu,

^a Kuan Chen,^a Zhengze Zhang^a and Yuan Zhang

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. China
E-mail: zhangyuan@lzu.edu.cn

^b First Hospital of Lanzhou University, Lanzhou University, China

Abstract

A Ce(III)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under mild conditions without the need for external photosensitizers.

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Article information

DOI: https://doi.org/10.1039/D2CC07071E
Article type: Communication
Submitted: 29 Dec 2022
Accepted: 02 Feb 2023
First published: 02 Feb 2023

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Chem. Commun., 2023,59, 2628-2631

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Visible-light-induced C_sp³–H functionalization of glycine derivatives by cerium catalysis

S. Wang, Y. Ye, Y. Hu, X. Meng, Z. Liu, J. Liu, K. Chen, Z. Zhang and Y. Zhang, Chem. Commun., 2023, 59, 2628 DOI: 10.1039/D2CC07071E

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Chemical Communications