Issue 34, 2023

Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant

Abstract

We have introduced a Friedel–Crafts alkylation strategy of a Ni-salphen complex as derived from 2-hydroxy-5-methoxybenzaldehyde, an isomer of biomass derived vanillin, to construct a Ni-salphen based porous organic polymer (Ni@T-POP). The X-ray absorption spectroscopy (XAS) analysis revealed the existence of Ni–N2O2 core sites in the Ni@T-POP framework, which demonstrates unprecedented catalytic efficiency towards oxidative decontamination of sulfur mustards (HD's) compared to its complex precursor.

Graphical abstract: Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant

Supplementary files

Article information

Article type
Communication
Submitted
25 Jan 2023
Accepted
28 Mar 2023
First published
29 Mar 2023

Chem. Commun., 2023,59, 5067-5070

Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant

P. Kalita, R. Paul, C. Pao, R. Chatterjee, A. Bhaumik and J. Mondal, Chem. Commun., 2023, 59, 5067 DOI: 10.1039/D3CC00349C

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