Issue 32, 2023, Issue in Progress
From the journal:

RSC Advances

Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations†

Yong Qiang Wan, ORCID logo a   Huaixin Hao, ORCID logo b   Lu Yu, ORCID logo a   Zhi Peng Wang*b  and  Pavle Mocilac ORCID logo *a  

* Corresponding authors

a School of Nuclear Science and Technology, Lanzhou University, Lanzhou, China
E-mail: pavlem@lzu.edu.cn
Tel: +86 18719828130

b Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, China
E-mail: wangzhipeng@mail.tsinghua.edu.cn
Tel: +86 18111567906

Abstract

Two novel bistriazolyl-phenanthroline (BTrzPhen) ligands, bearing benzene-sulphonate (DS-BTrzPhen) and amino-acidic (DAA-BTrzPhen) hydrophilizing moieties were developed and found to be more soluble in aqueous acidic media with improved selectivity for Am(III) over Eu(III) in solvent extraction studies having SFEu/Am values reaching >300. The remarkable activities of both ligands suggest that BTrzPhen ligands are generally still worth exploring and improving.

Graphical abstract: Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3RA02707D
Article type
Paper
Submitted
24 Apr 2023
Accepted
08 Jul 2023
First published
20 Jul 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 21982-21990

Permissions

Request permissions

Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations

Y. Q. Wan, H. Hao, L. Yu, Z. P. Wang and P. Mocilac, RSC Adv., 2023, 13, 21982 DOI: 10.1039/D3RA02707D

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements