Issue 7, 2024
From the journal:

Chemical Communications

Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(i) complex†

Heng Zhang,b   Yoshihiro Shimoyamaa  and  Yumiko Nakajima ORCID logo *ab  

* Corresponding authors

a Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

b School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan
E-mail: nakajima.y.ap@m.titech.ac.jp

Abstract

A Co(I) catalyst bearing a phenanthroline-based PNNP ligand (2,9-bis((diphenylphosphanyl)methyl)-1,10-phenanthroline) exhibits long-range metal ligand cooperation behavior using a ligand backbone as a hydrogen reservoir and catalyses hydrogenolysis of benzyl benzoate derivatives via β-C–O cleavage with atmospheric pressure H2.

Graphical abstract: Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(i) complex

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Article information

DOI
https://doi.org/10.1039/D3CC05354G
Article type
Communication
Submitted
31 Oct 2023
Accepted
12 Dec 2023
First published
18 Dec 2023

Chem. Commun., 2024,60, 823-826

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Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(I) complex

H. Zhang, Y. Shimoyama and Y. Nakajima, Chem. Commun., 2024, 60, 823 DOI: 10.1039/D3CC05354G

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