Issue 7, 2024
From the journal:

Chemical Communications

Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(i) complex†

Heng Zhang,b   Yoshihiro Shimoyamaa  and  Yumiko Nakajima ORCID logo *ab  

* Corresponding authors

a Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

b School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan
E-mail: nakajima.y.ap@m.titech.ac.jp

Abstract

A Co(I) catalyst bearing a phenanthroline-based PNNP ligand (2,9-bis((diphenylphosphanyl)methyl)-1,10-phenanthroline) exhibits long-range metal ligand cooperation behavior using a ligand backbone as a hydrogen reservoir and catalyses hydrogenolysis of benzyl benzoate derivatives via β-C–O cleavage with atmospheric pressure H2.

Graphical abstract: Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(i) complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3CC05354G
Article type
Communication
Submitted
31 Oct 2023
Accepted
12 Dec 2023
First published
18 Dec 2023

Chem. Commun., 2024,60, 823-826

Author version available


Download author version (PDF)

Permissions

Request permissions

Ester hydrogenolysis via β-C–O bond cleavage catalysed by a phenanthroline-based PNNP-cobalt(I) complex

H. Zhang, Y. Shimoyama and Y. Nakajima, Chem. Commun., 2024, 60, 823 DOI: 10.1039/D3CC05354G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements