Issue 55, 2024
From the journal:

Chemical Communications

Regulating iminophosphorane P[double bond, length as m-dash]N bond reactivity through geometric constraints with cage-shaped triarylphosphines†

Lei Hu,‡§ab   Sayandip Chakraborty,§a   Nikolay Tumanov, ORCID logo a   Johan Wouters,a   Raphaël Robiette ORCID logo *b  and  Guillaume Berionni ORCID logo *a  

* Corresponding authors

a Université de Namur, Department of Chemistry, Namur Institute of Structured Matter (NISM), Rue de Bruxelles 61, Namur 5000, Belgium
E-mail: guillaume.berionni@unamur.be

b Université Catholique de Louvain, Institute of Condensed Matter and Nanosciences, Place Louis Pasteur 1 box L4.01.02, Louvain-la-Neuve 1348, Belgium
E-mail: raphael.robiette@uclouvain.be

Abstract

Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

Graphical abstract: Regulating iminophosphorane P [[double bond, length as m-dash]] N bond reactivity through geometric constraints with cage-shaped triarylphosphines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D4CC01868K
Article type
Communication
Submitted
19 Apr 2024
Accepted
28 Apr 2024
First published
18 Jun 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7073-7076

Permissions

Request permissions

Regulating iminophosphorane P[double bond, length as m-dash]N bond reactivity through geometric constraints with cage-shaped triarylphosphines

L. Hu, S. Chakraborty, N. Tumanov, J. Wouters, R. Robiette and G. Berionni, Chem. Commun., 2024, 60, 7073 DOI: 10.1039/D4CC01868K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements