Issue 36, 2024
From the journal:

CrystEngComm

Solvent- and tatrz-induced single-crystal-to-single-crystal transformations within cobalt(ii)-triazole MOFs: a luminescent probe for frankincense†

Jialin Feng,‡a   Jianshuai Mu, ORCID logo ‡*a   Zhengyu Liu,‡a   Lin Cheng,*a   Siyu Li,a   Xin Cheng,a   Shaowei Zhang, ORCID logo *b   Xin Menga  and  Ying Wang ORCID logo *a  

* Corresponding authors

a College of Chemistry, Tianjin Normal University, Tianjin 300387, P.R. China
E-mail: hxxymujianshuai@tjnu.edu.cn, hxxycl@tjnu.edu.cn, hxxywy@tjnu.edu.cn

b School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of the Ministry of Education, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
E-mail: swzhang@hnust.edu.cn

Abstract

A 2D MOF, {[Co(tatrz)(ipa)]·H2O}n (1), with mixed ligands tatrz and ipa was isolated. Solvent exchange experiment indicated that the water molecule can be replaced by DMF as evidenced by the SC–SC transformation product of {[Co(tatrz)(ipa)]·DMF}n (2). When 1 is immersed in the tatrz solution, {[Co(tatrz)(ipa)(H2O)]·(tatrz)0.5}n (3) can be obtained, showing SC–SC transformation. Importantly, 3 represents the first luminescent sensor for frankincense.

Graphical abstract: Solvent- and tatrz-induced single-crystal-to-single-crystal transformations within cobalt(ii)-triazole MOFs: a luminescent probe for frankincense

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Article information

DOI
https://doi.org/10.1039/D4CE00360H
Article type
Communication
Submitted
13 Apr 2024
Accepted
31 Jul 2024
First published
10 Aug 2024

CrystEngComm, 2024,26, 4953-4957

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Solvent- and tatrz-induced single-crystal-to-single-crystal transformations within cobalt(II)-triazole MOFs: a luminescent probe for frankincense

J. Feng, J. Mu, Z. Liu, L. Cheng, S. Li, X. Cheng, S. Zhang, X. Meng and Y. Wang, CrystEngComm, 2024, 26, 4953 DOI: 10.1039/D4CE00360H

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