Issue 44, 2024

Structural transformation of silver(i)–thiolate coordination polymer film at solid–liquid interfaces

Abstract

We report that the ligand-exchange reaction between [Ag(o-SPhCO2H)]n deposited on a solid substrate and the free p-HSPhCOOH ligand in solution results in crystal transformation from [Ag(o-SPhCO2H)]n to [Ag(p-SPhCO2H)]n on the substrate. Structural analysis revealed a structural transformation between CPs with different topologies via ligand exchange.

Graphical abstract: Structural transformation of silver(i)–thiolate coordination polymer film at solid–liquid interfaces

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2024
Accepted
25 Oct 2024
First published
28 Oct 2024
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2024,26, 6269-6273

Structural transformation of silver(I)–thiolate coordination polymer film at solid–liquid interfaces

M. Fukuoka, Y. Takashima, K. Akamatsu, A. Demessence and T. Tsuruoka, CrystEngComm, 2024, 26, 6269 DOI: 10.1039/D4CE01023J

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