Crumpled graphene fully decorated with nickel-based nanoparticles applied in glyphosate detection

Abstract

Glyphosate (Glyp), a widely used herbicide, has raised significant concerns regarding its toxicological effects and potential risks to human health, particularly concerning water pollution. Hence, there is a critical need to monitor glyphosate levels in water bodies. This study introduces a novel approach for electrochemically detecting glyphosate in aqueous environments using crumpled graphene decorated with nickel-based nanoparticles (Ni:CG) synthesized in a single step. Cyclic voltammetry and chronoamperometry techniques were employed for detection. The cyclic voltammetry analysis revealed an impressive linear range with detection and quantification limits of 2.0 × 10⁻⁹ M and 6.0 × 10⁻⁹ M, respectively. Additionally, the method demonstrated excellent accuracy and precision at low concentrations, as evidenced by successful glyphosate recovery from distilled-deionized water and spike-and-recovery tests, at a significant level of 99.9%. Furthermore, interference tests conducted via chronoamperometry on the presence of Cu²⁺, Co²⁺, and Fe³⁺ cations showcased the superior performance of the Ni:CG electrochemical sensor. The synthesis of crumpled graphene-/nickel-based composites offers a promising avenue for the future of on-site glyphosate detection, presenting a robust and efficient solution to environmental challenges.