Issue 37, 2024

Facile preparation of UiO-66-NH2-stabilized high internal phase molecularly imprinted polymers for synergistic catalytic hydrolysis detoxification of organophosphate nerve agents

Abstract

Developing high-performance artificial enzyme materials with practical applications in efficient catalytic hydrolysis detoxification of organophosphate (OP) nerve agents remains a formidable challenge. Herein, UiO-66-NH2-stabilized Pickering high internal phase molecularly imprinted polymer systems (MOFs@PHIPMIPs) were developed using OPs as template molecules. Thus, UiO-66-NH2-doped high-internal-phase MIP composites were obtained, which integrate MIPs and MOFs successfully, showing remarkable catalytic hydrolysis activity towards OPs. In addition, by introducing methyl methacrylate (MMA) during copolymerization, the MOFs@PHIPMIPs would effectively acquire pH buffering properties. The multi-porous composite catalysis system exhibits an exceptionally high detoxification efficiency towards dimethyl-4-nitrophenyl phosphate (DMNP) in pure water (kobs = 0.9162 min−1, t1/2 = 0.76 min). This work presents a new strategy for the preparation of artificial phosphatase materials with high-performance catalytic detoxification of OPs with great application prospects.

Graphical abstract: Facile preparation of UiO-66-NH2-stabilized high internal phase molecularly imprinted polymers for synergistic catalytic hydrolysis detoxification of organophosphate nerve agents

Supplementary files

Article information

Article type
Paper
Submitted
18 Jun 2024
Accepted
15 Aug 2024
First published
22 Aug 2024

J. Mater. Chem. A, 2024,12, 25465-25474

Facile preparation of UiO-66-NH2-stabilized high internal phase molecularly imprinted polymers for synergistic catalytic hydrolysis detoxification of organophosphate nerve agents

Y. Niu, P. Jiang and T. Guo, J. Mater. Chem. A, 2024, 12, 25465 DOI: 10.1039/D4TA04230A

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