Issue 37, 2024

Nanostructured DyFeO3 photocatalyst: an authentic and effective approach for remediation of industrial and pharmaceutical wastewater

Abstract

The persistent issue of water contamination by industrial dyes and pharmaceutical residues has created an urgent need for advanced photocatalytic materials to effectively address environmental remediation. Despite ongoing research, developing novel photocatalysts with ideal band structures, high quantum yields, and strong stability remains a considerable challenge. In this study, we report the synthesis and detailed characterization of nanostructured dysprosium orthoferrite (DyFeO3) nanoparticles, designed with a porous architecture featuring an average pore size of 3.41 nm and a surface area of 23.25 m2 g−1 to enhance photocatalytic efficiency under solar irradiation. Using Inverse Fast Fourier Transform (FFT) analysis on selected areas of TEM images, we gained deeper insights into the formation and internal structure of these nanoparticles. DyFeO3 nanoparticles exhibit a direct band gap of 2.1 eV, making them particularly effective for solar light absorption. Comprehensive spectroscopic analyses, including Mott–Schottky measurements and valence band XPS, confirmed their n-type semiconducting nature and revealed an electronic band structure that supports efficient oxygen reduction and oxidation reactions. Additionally, time-resolved photoluminescence spectroscopy demonstrated a charge carrier lifetime of 2.43 ns, indicating efficient separation and transport of photogenerated charge carriers. The photocatalytic performance of DyFeO3 was evaluated through degradation experiments using two model pollutants: Rhodamine B (RhB) and Levofloxacin (LFX). The nanoparticles successfully degraded both the colored RhB and the colorless LFX, eliminating concerns of dye sensitization. Furthermore, the presence of DyFeO3 significantly reduced the activation energy for RhB degradation from 55.87 kJ mol−1 K−1 to 34.58 kJ mol−1 K−1 and for LFX from 38.4 kJ mol−1 K−1 to 34.1 kJ mol−1 K−1, demonstrating its catalytic efficiency. With apparent quantum yield values of 28.94% for RhB and 32.83% for LFX, these nanoparticles demonstrate exceptional solar energy harvesting capabilities. The high degradation efficiency, quantum yield, and stability of the single-structured DyFeO3 nanoparticles highlight their potential for large-scale applications in photocatalytic and environmental remediation technologies.

Graphical abstract: Nanostructured DyFeO3 photocatalyst: an authentic and effective approach for remediation of industrial and pharmaceutical wastewater

Supplementary files

Transparent peer review

To support increased transparency, we offer authors the option to publish the peer review history alongside their article.

View this article’s peer review history

Article information

Article type
Paper
Submitted
08 Jul 2024
Accepted
28 Aug 2024
First published
28 Aug 2024

J. Mater. Chem. A, 2024,12, 25475-25490

Nanostructured DyFeO3 photocatalyst: an authentic and effective approach for remediation of industrial and pharmaceutical wastewater

M. Tarek, F. Yasmeen and M. A. Basith, J. Mater. Chem. A, 2024, 12, 25475 DOI: 10.1039/D4TA04728A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements